Host Jeremy Clarkson welcomes more famous faces, all trying to win big money for their chosen charities.
On Tuesday's episode are Robert Rinder and Scarlett Moffatt. On Wednesday's episode are Jimmy Carr, Christine Ohuruogu and Alex Beresford.
On Thursday's episode are Meera Syal and Jim Moir, aka Vic Reeves. On Friday's episode are Harry Redknapp, Craig Charles and Sam Quek.
Who Wants To Be A Millionaire? Celebrity Specials begin Tuesday 16th November at 9pm on ITV.